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Beginner’s Guide to Platinum-Palladium Printing

Beginner’s Guide to Platinum-Palladium Printing

After years of fine art art printing experience, I finally got my nerve-up to try the ultimate: platinum-palladium printing

I recently made my first attempt at platinum-palladium printing. If you’re curious about it, watch my video and use the lists below to get you started. Have fun!

Step-by-Step Process

  1. Mix up the chemicals for the paper coating, developing, and clearing baths
  2. Coat the paper carefully and thoroughly, allow to dry at least 30 – 45 minutes
    I used the Bostick & Sullivan formula for coating an 8 x 10″ sheet:
    – Ferric Oxalate Solution #1 – 12 drops
    – Palladium Solution #3 – 12 drops
    – 5% Sodium Platinum Solution Na2 – 6 drops
  3. Sandwich coated paper and negative tightly under glass. A contact printing frame is recommended
  4. Expose to UV light (this could be the sun, but a controlled light source is recommended). In my particular setup, the exposure time was 2.5 minutes.
  5. Place exposed print into developing tray. Carefully but quickly pour developer over the entire sheet of paper. Print will develop almost immediately.
  6. Place developed print into the second bath, the clearing bath, which will clear the ferric oxalate solution from the print. This removes the yellow tint from the white areas in the print and help the print to be archival. Takes up to 15 minutes.
  7. Water bath: rinse the print thoroughly in fresh flowing water for up 30 – 45 minutes
  8. Dries flat in about 24 hours

IMPORTANT: The developer is reusable, so be sure to store it in a suitable container after use.

What you’ll need

Below is a list of materials you’ll need to make platinum-palladium prints

Paper

You’ll need unbuffered 100% cotton rag paper. (Standard watercolor paper is not recommended). The most highly recommended papers are:

An original 7 x 7-inch square platinum-palladium print on Hahnemühle Platinum Rag paper.
An original 7 x 7-inch square platinum-palladium print on Hahnemühle Platinum Rag paper.

Chemistry

Recommendation: Buy the beginner’s kit from Bostick & Sullivan. They put everything you need to get started into one easy package.

  • Ferric Oxalate Solution #1 – 25 ml
  • Palladium Solution #3 – 25 ml
  • 5% Sodium Platinum Solution Na2 – 10 ml
  • 3 plastic droppers
  • 32 oz.Potassium Oxalate Developer
  • 250 g EDTA clearing agent & 250 g Sodium Bisulfite for clearing
The three chemicals required to make the platinum-palladium sensitizing solution
The three chemicals required to make the platinum-palladium sensitizing solution

The Negative

Since platinum/palladium printing is a contact printing process, you’ll need a negative at the size of the final print. You can use a large format negative, an LVT film negative imaged from a digital file, or a high-quality digital negative made on transparency film on an inkjet printer.

A digital inkjet negative printed on Pictorico transparency film.
A digital inkjet negative printed on Pictorico transparency film.
A negative imaged onto real TMAX 100 film with an LVT machine from a digital file.
A negative imaged onto real TMAX 100 film with an LVT machine from a digital file.

Other Tools and Materials

  • Pictorico brand inkjet transparency film for the negative (AND access to a good quality inkjet printer)
  • Contact printing frame or reasonable facsimile
  • Paint brushes for coating the paper (some people prefer a special glass coating rod)
  • Plastic darkroom trays for the three baths (developer, clearing bath, water)
  • Darkroom tongs for each tray
  • Shot glass or other small plastic container for mixing the platinum-palladium solution
  • UV light source (see below)
  • Rubber gloves, eye protection, a face mask, and an apron
  • Glass jar for water to wet and rinse brushes
  • Optional: Archival print washer
  • Distilled water
  • Paper towels
  • Plastic funnels
Contact Printing frames are specifically made for contact printing. They hold the negative tight against the paper and the folding back (shown below) allows you to check the exposure of the print without shifting the negative out of place.
Contact Printing frames are specifically made for contact printing. They hold the negative tight against the paper and the folding back (shown below) allows you to check the exposure of the print without shifting the negative out of place.
 This image shows the the folding back of a contact printing frame, which allows you to check the exposure of the print without shifting the negative out of place.
This image shows the the folding back of a contact printing frame, which allows you to check the exposure of the print without shifting the negative out of place.

UV Light Source

High-end platinum printers use large and well-made UV light boxes, but a much more rudimentary setup can get you started. For my starting setup, I used a simple LED UV light found on Amazon, fitted into hole cut into a cardboard box that’s large enough to cover the contact printing frame.

To my surprise, these affordable little UV lights worked very well.

I ordered a two-pack of these LED lights very affordably from Amazon. One unit is all I needed to make the 8 x 10" prints.
I ordered a two-pack of these LED lights very affordably from Amazon. One unit is all I needed to make the 8 x 10″ prints.

Amazon: Glostars 100W LED UV Black Light, Powerful UV Spotlight, IP66, 395nm Lamp (2 pack)

Some of my first ever platinum-palladium prints

An old Chevy Truck by Keith Dotson. Platinum Palladium Print on Hahnemuhle Platinum Rag paper. 7" x 7", Edition of 8 plus 2 artist proofs. Signed and numbered on the back in pencil.
An old Chevy Truck by Keith Dotson. Platinum Palladium Print on Hahnemuhle Platinum Rag paper. 7″ x 7″, Edition of 8 plus 2 artist proofs. Signed and numbered on the back in pencil. Buy a print.
Farmer's Exchange Co-op by Keith Dotson. Platinum-palladium print on Hahnemuhle Platinum Rag Paper. 6 x 9" in an edition of 8 plus two artist proofs. Signed and numbered on the back in pencil.
Farmer’s Exchange Co-op by Keith Dotson. Platinum-palladium print on Hahnemuhle Platinum Rag Paper. 6 x 9″ in an edition of 8 plus two artist proofs. Signed and numbered on the back in pencil. Buy a print.
Raven on a Dead Tree in the Guadalupe Mountains of Texas - 7 x 7" handmade platinum/palladium limited edition print by Keith Dotson. Edition of 8 plus two artist proofs. Signed and numbered on the back.
Raven on a Dead Tree in the Guadalupe Mountains of Texas – 7 x 7″ handmade platinum/palladium limited edition print by Keith Dotson. Edition of 8 plus two artist proofs. Signed and numbered on the back. Buy a print.

NOTE: Contains Amazon Affiliate links. I may receive a small commission on qualifying purchases.

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